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Purification and Functionalisation of Nitrogen-Doped Single-Walled Carbon Nanotubes

机译:氮掺杂单壁碳纳米管的纯化和官能化

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Nitrogen doped single-walled carbon nanotubes has been prepared using the arc discharge method. The material contains in average more impurities like pristine (pure) carbon nanotube material produced with the same method. We have tested several purification methods like the oxidation in hot air. First tests have shown that nitrogen-doped nanotubes exhibit a higher reactivity and are therefore less inert towards oxidative purification methods used for carbon nanotubes. We want to present a new purification method. It is based on the oxidation of the carbon impurities, homogeneously dispersed in boiling tertrachloroethan under airflow. The purity of the sample was investigated using scanning electron microscopy and transmission electron microscopy. Another part will present the characterization of chemically modified nitrogen-doped nanotubes after purification and first steps of the functionalisation of the hetero-nanotube material. Because of already existing model systems with hetero fullerenes, we have chosen a `Mannich'-like reaction for the modification of nitrogen-doped nanotubes.
机译:使用电弧放电方法制备氮掺杂的单壁碳纳米管。该材料平均含有具有相同方法的原始(纯)碳纳米管材料等杂质。我们已经测试了几种纯化方法,如热空气中的氧化。第一次试验表明,氮掺杂的纳米管表现出更高的反应性,因此对于用于碳纳米管的氧化纯化方法较低。我们想提出一种新的净化方法。它基于碳杂质的氧化,在气流下均匀地分散在沸腾的脱乙酰氯乙烷中。使用扫描电子显微镜和透射电子显微镜研究样品的纯度。另一种部分将在纯化后呈现化学改性的氮掺杂纳米管的表征和杂纳米管材料的官能化的第一步骤。由于已经存在具有杂富勒烯的模型系统,我们选择了用于改性氮掺杂纳米管的`mannich'-liply反应。

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