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ELECTRICAL AND THERMAL CONDUCTIVITIES OF AU NANOPARTICLE DECORATED GRAPHENE NANOPLATELET 'PAPER'

机译:Au纳米粒子的电气和热导体装饰石墨烯纳米薄板'纸'

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Numerous research efforts are underway directed at discovering the superior and unique properties of single layer graphene and multilayer graphene nanoplatelets. Typical methods to synthesize metal nanoparticle on graphene surface involve covalent functionalization of graphene surface to induce anchoring sites for the metal precursor and subsequent attachment of the reduced nanoparticles to the surface. This approach results in the disruption of the sp2 bonded carbon atoms in the basal plane which leads to reduced transport properties of the graphene because of additional scattering sites. Another widely adopted technique involves nanoparticle growth on non-covalently functionalized graphene surfaces, which preserves the intrinsic properties of graphene nanosheets thanks to the minimum chemical perturbation of the basal planes. Other techniques of metal nanoparticle decoration on graphitic nanostructure include electrodeposition, evaporation, solventless bulk synthesis and etc. While these methods have some processing advantages over solution-phase techniques, they are usually quite expensive and energy intensive.
机译:正在进行许多研究工作,目前正在发现单层石墨烯和多层石墨烯纳米孔的优越和独特的性质。在石墨烯表面上合成金属纳米颗粒的典型方法涉及石墨烯表面的共价官能化,以诱导金属前体的锚定位点,并随后将还原纳米颗粒的附着在表面上。该方法导致基底平面中的SP2键合碳原子中断,这导致石墨烯的运输特性降低,因为额外的散射位点。另一种普遍采用的技术涉及非共价官能化的石墨烯表面上的纳米颗粒生长,这归因于基底平面的最小化学扰动,可以保留石墨烯纳米液的内在特性。在石墨纳米结构上的其他金属纳米粒子装饰技术包括电沉积,蒸发,无溶剂类散装合成等。虽然这些方法具有与解决方技术相比的一些加工优势,但它们通常具有相当昂贵和能量密集的。

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