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VISUALIZATION OF MICRO-AND MACROMIXING IN LIQUID MIXTURES OF REACTING COMPONENTS

机译:在反应组分的液体混合物中可视化微型和宏观激增

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Micromixing is visualized inside a stirred vessel by using two different optical measurement techniques, the optical tomography and the Planar Laser Induced Fluorescence technique (PLIF). In order to distinguish between macro- and micromixing, a mixture of two dyes is injected into the mixing vessel. One of the dyes is an inert dye whereas the second dye is undergoing a fast chemical reaction with the vessel content. The distribution of the inert dye serves as a tracer for the macromixing but does not predicate the mixing quality on the nano scale. The chemical reaction requires mixing on the molecular scale. Therefore the reacting dye, which is changing its emission characteristics during the reaction, indirectly visualizes the micromixing. The tomographical dual wavelength photometry is used to measure the three-dimensional, transient concentration fields in the whole vessel at the same time. Measurements with the Planar Laser Induced Fluorescence technique are performed in an arbitrary plane of the vessel. This restriction on a two-dimensional concentration field is, recompensed with a much higher spatial resolution which allows to visualize small scale structures in the order of mm. For both techniques low Reynolds number measurements are performed in a mixing vessel equipped with a Rushton turbine. Results are presented as two- or three- dimensional concentration fields. Areas of micromixing are detected by calculating the local degree of deviation from the concentration fields. They are depending on the injection position of the dye and are mainly found in the boundary layer of the lamellas.
机译:通过使用两种不同的光学测量技术,光学断层扫描和平面激光诱导的荧光技术(PLIF),通过使用两种不同的光学测量技术在搅拌容器内部可视化微混合。为了区分宏观和微混合,将两种染料的混合物注入混合容器中。其中一种染料是惰性染料,而第二染料经历了与血管含量的快速化学反应。惰性染料的分布用作宏观混合的示踪剂,但不会使纳米级上的混合质量引起。化学反应需要在分子尺度上混合。因此,在反应过程中改变其排放特性的反应染料间接可视化微混合。截障地形双波长光度测量用于同时测量整个容器中的三维瞬态浓度场。使用平面激光诱导的荧光技术的测量在容器的任意平面中进行。对二维浓度字段的这种限制是重新组用的,其空间分辨率更高,其允许按摩的顺序可视化小规模结构。对于这两种技术,低雷诺数量测量在配备有拉什顿涡轮机的混合容器中进行。结果呈现为两维​​或三维浓度场。通过计算与浓度场的局部偏差程度来检测微混合区域。它们取决于染料的注射位置,主要发现在薄片的边界层中。

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