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STEADY-STATE BURNING OF A SCAVENGED SOLID COMPOSITE PROPELLANT

机译:清除固体复合推进剂的稳态燃烧

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Steady-state burning of a propellant containing, by mass, 82% of a mixture of ammonium perchlorate and sodium nitrate, 14% HTPB, and 4% Al was investigated in a constant pressure bomb up to 7 MPa of nitrogen. Two different regions of burning rate versus pressure dependence were found: r_b = 0.326 p~(0.79) mm/s, for 1.1 < p < 5.0 MPa, and r_b = 3.33 p~(0.50) mm/s for p > 5.0 MPa. At pressures less than 1.1 MPa, steady state burning of the propellant could not be observed. Independent investigation of the similar composite propellant containing only AP as oxidizer gave the dependence: r_b = 0.450 p~(0.48) mm/s in the pressure interval 0.1 to 7 MPa. The main result in this respect consists in that the burning rate versus pressure relations are similar for both formulations under high pressure, p >5.0 MPa, (with the exception that burning rate of the SN propellant is slightly less) and quite different in the lower pressure interval. The basic assumption discussed in this paper consists in that for propellant burning in the lower pressure region the very reactive chlorine oxides are eliminated by a reaction with sodium nitrate, and burning rate is determined by the NO_x oxidation processes similar to those defining burning rate of double-base propellants. In the high pressure region the independent burning of the HTPB and small particles of AP and Al interrelation becomes effective, and the process of heat generation is implemented basically in the zone where ClO_x oxidation reactions prevail.
机译:在恒压轰炸中,在高达7MPa的氮气中,研究了含有质量的推进剂的推进剂的推进剂的稳定燃烧,含有硝酸铵和硝酸钠,14%HTPB和4%Al。发现了两个不同的燃烧速率区域与压力依赖性:R_B = 0.326 p〜(0.79)mm / s,对于1.1 <5.0MPa,以及用于P> 5.0 MPa的R_B = 3.33 P〜(0.50)mm / s。在小于1.1MPa的压力下,无法观察到推进剂的稳态燃烧。独立于仅含有Ap作为氧化剂的类似复合推进剂的独立研究使得依赖性:R_B = 0.450p〜(0.48)mm / s在压力间隔0.1至7MPa中。这方面的主要原因包括燃烧率与压力关系相似,对高压,P> 5.0MPa的配方相似,(除了SN推进剂的燃烧率略低于较低的燃烧率)和较低的不同之处压力间隔。本文中讨论的基本假设包括:对于在较低压力区域中燃烧的推进剂,通过与硝酸钠的反应消除非常反应性的氯氧化物,并且通过类似于定义双重燃烧速率的NO_X氧化方法确定燃烧速率。 -Base推进剂。在高压区域中,HTPB的独立燃烧和AP和Al相互关联的小颗粒变得有效,并且发热过程基本上在CLO_X氧化反应的占上风的区域中实现。

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