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Characterization of doped glasses manufactured by sintering of nanoparticles

机译:纳米颗粒烧结制造的掺杂眼镜的特征

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Gold ruby glass is conventionally manufactured by melting technology. Disadvantageous is the difficulty to control size and distribution of the nanosized gold particles. In order to diminish these disadvantages, the samples of this study are manufactured by sintering of silica green bodies. Here, a homogeneous and sharp pore size distribution can be realized, because the pore size is a function of the particle size of the powder used. These green bodies are impregnated with gold salt solutions. Since the forming gold particles are incorporated within the pores, their size and distribution should be governed by the pore size of the green body. In this paper, different colored samples are investigated by means of optical spectroscopy. UV-VIS transmission spectra, FT-IR and Raman spectra of sintered gold ruby glass are shown and compared to commercially available glasses. Differences occur mainly due to the different doping concentrations and the different matrix glass compositions.
机译:金红宝石玻璃通常通过熔化技术制造。不利的是难以控制纳米型金颗粒的尺寸和分布。为了减少这些缺点,本研究的样品通过烧结二氧化硅生坯制造。这里,可以实现均匀和尖锐的孔径分布,因为孔径是所用粉末的粒度的函数。这些生坯浸渍有金盐溶液。由于形成的金颗粒在孔内掺入,因此它们的尺寸和分布应受到绿体的孔径的控制。在本文中,通过光谱研究了不同的样品。示出了烧结金红宝石玻璃的UV-VIS透射光谱,FT-IR和拉曼光谱,并与市售的眼镜进行比较。差异主要是由于不同的掺杂浓度和不同的基质玻璃组合物。

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