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The Influence ofIIn-Situ Clad Straining on the Corrosion of Zircaloy in a PWR Water Environment

机译:对锆水环境渗透腐蚀的影响对PWR水环境的影响

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Zircaloy fuel element cladding changes dimensions during service in a pressurized water reactor (PWR) as a result of stress-free irradiation-induced growth, creep-driven by fuel pellet expansion and hydriding. The application of a tensile load in a high-temperature autoclave environments has previously been reported to increase the corrosion rate of Zircaloy, and heat treatments (beta quenching) that reduce the irradiation-induced stress-free growth of Zircaloy have previously been reported to reduce Zircaloy corrosion in-reactor. However, the effect of in-situ straining on Zircaloy corrosion in a PWR environment has not been systematically studied and reported in the literature. This paper presents experimental results regarding the effect of in-situ straining on Zircaloy corrosion in a PWR environment, both in-reactor and in an autoclave. In-situ electrochemical data and post-test metallographic data are presented. In-situ straining is seen to increase the corrosion rate of the Zircaloy, likely by breaking the passivating layer that is forming on the surface. However, the effect is a function of the applied strain rate.
机译:由于无应力照射诱导的生长,通过燃料颗粒膨胀和水合的增长,锆瓦尔燃料元件包层在加压水反应器(PWR)中的使用过程中的尺寸改变尺寸。先前据报道,在高温高压釜环境中施加拉伸载荷以增加锆瓦洛的腐蚀速率,并据报道,预先据报道以降低锆卤育的辐射辐射的无应力生长的热处理(β猝灭)反应堆中的锆铝腐蚀。然而,在文献中尚未系统地研究了原位紧张对PWR环境中锆铝腐蚀的影响。本文介绍了原位紧张对锆型腐蚀在PWR环境中的原位紧张效果的实验结果,反应堆和高压釜中。提出了原位电化学数据和测试后金相数据。可以通过破坏形成在表面上形成的钝化层来提高原位断裂以增加锆瓦洛的腐蚀速率。然而,效果是应用应变速率的函数。

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