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Combustion Synthesis Effects on the Powder Properties of Cerium Activated Yttrium Silicate Phosphor

机译:燃烧合成对铈活化钇硅酸盐磷光剂粉末性能的影响

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A potential blue-emitting phosphor, cerium activated yttrium silicate, (Y_(1-m)Ce_m)_2SiO_5, for field emission flat-panel displays was produced via a novel synthesis technique called combustion synthesis. Combustion synthesis involves a highly exothermic reaction between oxidizing metal nitrates and an organic fuel. The reaction temperature was found to be influenced by varying the fuel-to-oxidizer ratio to produce fuel-rich and fuel-lean reactions. In turn, the physical properties, such as crystallite size, pore volume, carbon contamination and surface area, and the luminescent characteristics were also found to be dependent on the fuel-to-oxidizer ratio. A sixty percent fuel-rich reaction was found to yield phosphor powders with the least carbon contamination, largest crystallite sizes and highest luminescent emission. This is also the first use of a fine size particle (SiO_2) solid suspended in the reaction solution which was found to be totally consumed to produce the silicate.
机译:通过新的合成技术产生潜在的蓝色发光磷光体,用于场发射平板显示器的硅酸钙,硅酸盐硅酸盐(Y_(1-M)CE_M)_2SIO_5。燃烧合成涉及氧化金属硝酸盐和有机燃料之间的高热反应。发现反应温度通过改变燃料到氧化剂比而影响,以产生富含燃料和燃料贫反应的影响。反过来,还发现物理性质,例如微晶尺寸,孔体积,碳污染和表面积,以及发光特性依赖于燃料 - 氧化剂比。发现富含富含碳污染,最大微晶尺寸和最高发光排放的富含富含燃料富燃料的反应。这也是第一次使用悬浮在反应溶液中的细小粒子(SiO_2)固体的使用,所述反应溶液被发现完全消耗以产生硅酸盐。

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