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Flow Behaviour of Gas-Containing LDPE/i-PP Melts

机译:含气体的LDPE / I-PP熔体的流动性能

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An experimental study was conducted to investigate the rheological behaviour and extrudate swell of polyolefin blends based on two grades of low-density polyethylene (LDPE) and an isotactic polypropylene (i-PP). Blending was carried out on a twin-screw extruder "Brabender" at different composition ratios in the temperature range from 140 to 190°C. The LDPE/i-PP blends mixed with 0.5 wt.% blowing agent were extruded by means of "Brabender" extrusiograph at melt temperature of 200°C and different extrusion rates. The influence of composition content on the viscosity and extrudate swell was considered. The foam structure and morphology are discussed in terms of shear rate, molecular characteristics and composition content. The presence of layered structure was observed: an outer smectic layer and an inner partially crystalline layer. The thickness of smectic layer and size of spherulites were determined.
机译:进行了实验研究以研究基于两种低密度聚乙烯(LDPE)和全同立构聚丙烯(I-PP)的聚烯烃共混物的流变行为和挤出物溶胀。在双螺杆挤出机“Brabender”中在不同的组成比的温度范围为140-190℃。将LDPE / I-PP混合物与0.5重量%混合。通过“Brabender”熔融温度为200℃和不同挤出率的挤出剂挤出%发泡剂。考虑了组合物含量对粘度和挤出物溶胀的影响。在剪切速率,分子特性和组成含量方面讨论了泡沫结构和形态。观察到层状结构的存在:外近晶层和内部晶体层。测定近晶层的厚度和球晶的尺寸。

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