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HIGH FIELD MAGNETOCONDUCTIVITY OF IODINE DOPED HELICAL POLYACETYLENE

机译:碘掺杂螺旋聚乙炔的高场磁导率

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The effect of interfibrillar interaction on the charge transport of doped polyacetylene is investigated by studying the high field magnetoconductivity of iodine doped helical polyacetylene. The zero-field resistivity ratio, (rho)_r = rho(1.2 K)/rho(300 K). is comparable to that of stretch-oriented high-density polyacetylene, which indicates the partial alignment of chains inside a polymer fiber. At low magnetic fields, the small negative component of magnetoconductivity was observed and its magnitude increases as the (rho)_r value increases. In the high field region, the magnetoconductivity is positive and it clearly shows the linear dependence on the magnetic field up to H = 30 T. The linear field dependence of magnetoconductivity is different from what is expected in the three-dimensional weak localization picture. For the same (rho)_r value samples, the magnitude of negative magnetoconductivity of S-polyacetylene is much bigger than that of R-polyacetylene, which could be attributed to the difference in the degree of helicity determining the strength of interfibrillar interaction.
机译:通过研究碘掺杂螺旋聚乙炔的高场磁导性研究了interfibrillar相互作用对掺杂聚乙炔的电荷传输的影响。零场电阻率比(RHO)_R = RHO(1.2K)/ RHO(300k)。与拉伸的高密度聚乙炔相当,表明链条内链的部分取向。在低磁场处,观察到磁导性的小负分量,并且随着(RHO)_R值增加,其幅度增加。在高场区域中,磁导性是阳性的,并且它清楚地示出了对高达H = 30t的磁场上的线性依赖性。磁导率的线性场依赖性与三维弱定位图片中的预期不同。对于相同的(Rho)_R值样品,S-聚乙炔的负磁导率的大小远大于R-聚乙炔的大小,这可能归因于确定纤维纤维结合强度的肝脏程度的差异。

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