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Simplifying the Thermodynamic Modeling of Asphaltenes in Upstream Operations

机译:简化上游操作中沥青质的热力学建模

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The development of a thermodynamic model to predict the onset of asphaltene precipitation is usually hindered by the complexity of the mixture under consideration. In an attempt to simplify asphaltene modeling, a model related to the Flory—Huggins theory had been previously proposed. The model is based on the fact that asphaltene stability depends upon the quality of the surrounding medium, expressed in terms of the solubility parameter. Moreover, the model only takes into account the first asphaltenes that come out of the solution. This allows the theoretical determination of one of the parameters starting from the concept of infinite dilution, as described in this work. This paper also presents a discussion about the optimal way of determining the parameters of the proposed model.
机译:热力学模型的开发预测沥青质沉淀的发作通常受到在考虑的混合物的复杂性的影响。为了简化沥青内建模,先前已经提出了与福伦 - Huggins理论相关的模型。该模型基于沥青质稳定性取决于周围介质的质量,以溶解度参数表示。此外,该模型仅考虑了从解决方案中出来的第一个沥青质。这允许从无限稀释的概念开始的理论测定,如本工作中所述。本文还介绍了确定所提出的模型参数的最佳方式。

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