首页> 外文会议>Intersociety Energy Conversion Engineering Conference >Studies on capacity fade of spinel based Li-ion batteries
【24h】

Studies on capacity fade of spinel based Li-ion batteries

机译:基于尖晶石锂离子电池的容量衰落研究

获取原文

摘要

This paper focuses on studying the performance of Li-ion cells using LiMn{sub}2O{sub}4 as the positive electrode material. The capacity of the cell has been optimized based on varying the charging current and the end potential. The capacity fade of these batteries has been studied at different charge currents, namely 0.1 A, 0.25 A, 0.5 A, 0.75 A and 1 A. The discharge rate for all cells was kept constant at 1 A. The lowest capacity fade is seen for the cell charged at 0.5 A indicating that this was optimum charging current for these batteries. For all charge currents, the resistance of the LiMn{sub}2O{sub}4 cathode remains lower than that of the carbon anode with cycling. This result is in contrast with cells made with LiCoO{sub}2 cathode where the increase in cathode resistance with cycling causes the fade in capacity. XRD studies of carbon and LiMn{sub}2O{sub}4 at different cycles, reveals no structural changes. However, the lattice constants vary with cycling indicating changes in the lithium intercalated at both electrodes. Further studies are being done to understand the cause for the capacity fade.
机译:本文侧重于使用LiMn {Sub} 2O} 4作为正极材料来研究锂离子电池的性能。基于改变充电电流和最终电位,细胞的容量已经过优化。已经在不同的电荷电流中研究了这些电池的容量衰落,即0.1a,0.25a,0.5a,0.75a和1a。所有细胞的放电率保持恒定在1 a。看到最低容量褪色该电池充电在0.5A,表明这对于这些电池来说是最佳的充电电流。对于所有电荷电流,LiMn {Sub} 2O {Sub} 4阴极的电阻仍然低于循环碳阳极的电阻。该结果与用LiCoO {Sub} 2阴极制成的电池形成对比,其中阴极电阻的增加导致容量的衰落。不同循环的碳和跛行{Sub} 4的XRD研究显示没有结构性变化。然而,晶格常数随着在两个电极中插入锂中的循环变化而变化。正在进行进一步的研究以了解能力褪色的原因。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号