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Transport Properties of a Kinetic Model for Chemical Reactions without Barriers

机译:无障碍障碍的化学反应动力学模型的运输特性

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A kinetic model of the Boltzmann equation for chemical reactions without energy barrier is considered here with the aim of evaluating the reaction rate and characterizing the transport coefficient of shear viscosity for the reactive system. The Chapman-Enskog solution of the Boltzmann equation is used to compute the chemical reaction effects, in a flow regime for which the reaction process is close to the final equilibrium state. Some numerical results are provided illustrating that the considered chemical reaction without energy barrier can induce an appreciable influence on the reaction rate and on the transport coefficient of shear viscosity.
机译:这里考虑了没有能量屏障的化学反应的Boltzmann方程的动力学模型,目的是评估反应速率并表征反应系统的剪切粘度的输送系数。 Boltzmann公式的Chapman-Enskog解决方案用于计算化学反应效果,在反应过程接近最终均衡状态的流动状态下。提供了一些数值结果,说明没有能量屏障的考虑化学反应可以对反应速率和剪切粘度的传输系数引起可明显的影响。

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