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VAPOUR DEPOSITION OF CORROSION RESISTANT Zn-ALLOY COATINGS IN THE COIL COATING MODE

机译:在线圈涂布模式下耐腐蚀Zn合金涂层的气相沉积

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Coil coating is state of the art for the production of electroplated or hot-dip-plated steel sheets for automobile bodies. Vapour deposition techniques in the coil coating mode are up to now only used industrially for metallizing polymers and for deposition of very thin and barrier coatings on various substrates. In the last years many studies on ion beam assisted deposition (IBAD) coatings on metals and insulators for wear reduction and corrosion protection have been made. However the IBAD deposition of larger areas ( ≥10 cm x 10 cm) is still a major problem. Therefore we have developed a coil coater running inside an IBAD deposition chamber and allowing very flexible deposition modes. Single layers, multilayers and alloy layers can be deposited under ion bombardment on metal strips 30 cm wide. A number of examples dealing with Zn-alloy coatings on low alloy steel are reported: pure Zn-coatings were compared with Zn/Ti-, Zn/Cr-, and Zn/Mn-alloys. In some cases also multilayers of the different metals were studied in both static and dynamic operation modes. The coatings had a thickness of 2-8 um and their corrosion behaviour was investigated by salt spray tests. The micro structure and composition of the coatings was studied by scanning electron microscopy and EDX analysis. The behaviour of the coating/substrate system is discussed in comparison with "state-of the-art" Zn-coatings produced by electro-galvanizing. Generally speaking the performance of the optimised coatings is as good or better as the reference standard.
机译:线圈涂层是用于生产汽车体的电镀或热浸镀钢板的技术领域。线圈涂覆模式中的气相沉积技术达到现在仅在工业上用于金属化聚合物并用于在各种基材上沉积非常薄的屏障涂层。在过去几年中,许多关于离子束辅助沉积(IBAD)涂层的研究,用于耐磨和腐蚀保护的金属和绝缘体上。然而,较大区域的IBAD沉积(≥10cm×10cm)仍然是一个主要问题。因此,我们已经开发了在IBAD沉积室内运行的线圈涂布机,并允许非常灵活的沉积模式。可以在30cm宽的金属条上沉积单层,多层和合金层,在离子轰击下沉积。报道了在低合金钢上处理Zn合金涂层的许多例子:将纯Zn涂层与Zn / Ti,Zn / Cr-和Zn / Mn合金进行比较。在某些情况下,在静态和动态操作模式下,研究了不同金属的多层。涂层的厚度为2-8μm,并通过盐雾试验研究了它们的腐蚀行为。通过扫描电子显微镜和EDX分析研究涂层的微结构和组成。与通过电镀锌产生的“现有技术”Zn涂层相比,讨论了涂层/衬底系统的行为。一般而言,优化涂层的性能与参考标准一样好或更好。

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