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Effect of ozone bleaching on the fibre properties of pine and birch kraft pulp

机译:臭氧漂白对松桦牛皮纸纤维性质的影响

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Pine and birch kraft pulps were bleached with a TCF sequence including an ozone stage. Different ozone charges were used to obtain pulps with different final brightnesses (between 85 and 92percent). Pulps bleached with an ECF sequence or a TCF sequence in which ozone was replaced by peracetic acid were used as references. Main focus was on fibre deformation (curl and kink indexes) and how this was affected by ozone chage. The effect of fibre deformation on zero-span index and paper strength was also considered. No major differences in the degree of fibre deformation were observed directly after the ozone stage. After final bleaching with alkaline hydrogen peroxide, there was a clear trend towards greater curl and kink indexes with increasing ozone chage. A similar effect was seen in the case of zero-span index. Some straigthening of the fibres occurred int he final alkaline bleaching stage, depending on the carboxyl group content of the pulps. A connection was found between kink index and both zero-span index and tensile index of pine and birch pulps. There were also indications of a connection between fibre deformation and tear index of pine pulps.
机译:用包括臭氧阶段的TCF序列漂白松树和桦木牛皮纸。使用不同的臭氧电荷来获得具有不同最终亮度的纸浆(在85到92°之间)。用ECF序列或TCF序列漂白,其中臭氧被过乙酸代替作为参考。主要重点是纤维变形(卷曲和扭结指数)以及如何受臭氧凹槽的影响。还考虑了纤维变形对零跨度指数和纸张强度的影响。在臭氧阶段之后直接观察到纤维变形程度的主要差异。用碱性氢过氧化氢末端漂白后,较大的卷曲和扭结指数呈透明趋势随着臭氧凹槽的增加。在零跨度指数的情况下看到了类似的效果。纤维的一些尖端发生,int最终碱性漂白阶段,取决于纸浆的羧基含量。在Kink指数和松枝纸浆的零跨度指数和拉伸指数之间发现了一种连接。还有纤维变形与松油撕裂指数之间的连接的迹象。

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