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Effect of temperature and high pressure on conductive behavior of polyacene quinone radical polymers

机译:温度和高压对聚乙基醌自由基聚合物导电性能的影响

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The authors measured the DC conductivity of two polyacene quinone radical type polymers as a function of pressure at various temperatures. It was found that there is a kink at about 2.5 kbar on plots of log conductivity versus the square root of applied pressure in the range from 0.6 to 10 kbar, and that DC conductivity-temperature curves, even in the higher temperature region (300-400 K), also obey Mott's T/sup 1/4/-law. This may be due to the jump of an electron to the state nearer in space with a considerable energy barrier.
机译:作者测量了两种聚乙烯醌自由基聚合物的直流电导,作为各种温度的压力的函数。 结果发现,在测量电导率的曲线图中,在0.6至10 kbar的施加压力范围内的平方根,并且即使在较高温度区域中,直流电导率 - 温度曲线(300- 400 k),也服从Mott的T / Sup 1/4 / 4。 这可能是由于电子与具有相当能量屏障更接近空间的电子。

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