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Effect of temperature and high pressure on conductive behavior of polyacene quinone radical polymers

机译:温度和高压对并苯醌自由基聚合物导电性能的影响

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The authors measured the DC conductivity of two polyacene quinone radical type polymers as a function of pressure at various temperatures. It was found that there is a kink at about 2.5 kbar on plots of log conductivity versus the square root of applied pressure in the range from 0.6 to 10 kbar, and that DC conductivity-temperature curves, even in the higher temperature region (300-400 K), also obey Mott's T/sup 1/4/-law. This may be due to the jump of an electron to the state nearer in space with a considerable energy barrier.
机译:作者在不同温度下测量了两种聚丙烯并苯醌自由基型聚合物的直流电导率与压力的关系。发现在对数电导率与施加压力的平方根在0.6至10 kbar范围内的曲线上存在一个约2.5 kbar的扭结,即使在较高温度区域(300-300°C),直流电导率-温度曲线也存在。 400 K),也要遵守Mott的T / sup 1/4 /定律。这可能是由于电子跃迁到具有相当大的能垒的空间附近的状态。

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