SOLID STATE ELECTROTERANSPORT OF OXYGEN IN PRASEODYMIUM

摘要

The solid state electrotransport (SSE) is one of the most promising methods for the elimination of gaseous impurities from chemically active metals, such as rare earth metals. In the present work, the SSE process was applied for the oxygen removal from praseodymium. The SSE factors, such as effective valence, were measured under the various temperatures, electric field intensities and initial oxygen contents, and the effects of those conditions on the SSE process were discussed. Furthermore, the solubility of oxygen in solid praseodymium was also measured by using the SSE method and metal-oxide equilibrium method.