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NITROGEN-CONTAINING CARBONACEOUS MATERIALS VIA HYDROTHERMAL CARBONIZATION

机译:含氮碳质材料通过水热碳化

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Introduction Recently, nitrogen-containing carbon materials have attracted particular interest due to their remarkable performance in industrially and environmentally important applications, such as CO_2 sequestration[1], adsorption[2], purification[3], catalysts (or as catalysts supports)[4], or in electrochemistry (e.g. as supercapacitors, cells and batteries)[5]. The nitrogen dopant acts to improve both the structural and physicochemical properties of such materials for various desired end applications. However, the traditional methods for production of such materials rely on harsh and multistep processes, typically involving high temperature treatment and often leading to the generation of significant quantities of waste, whilst in some cases the overall carbon yield of the process is rather limited. Furthermore, conventional nitrogen-containing precursors (e.g. poly(aniline)) are not necessarily sustainable and relatively expensive as compared to, for example, abundant biomass-derived precursors.
机译:介绍最近,由于其在工业上和环保应用中的显着性能,例如CO_2螯合[1],吸附[2],纯化[3],催化剂(或催化剂支持),含氮碳材料引起了特别的兴趣。 4],或电化学(例如作为超级电容器,细胞和电池)[5]。氮掺杂剂作用以改善这种材料的结构和物理化学性质,用于各种所需的最终应用。然而,传统的生产这些材料的制造方法依赖于苛刻和多步的过程,通常涉及高温处理,并且通常导致大量废物的产生,同时在某些情况下,该过程的整体碳产量相当有限。此外,与例如丰富的生物质衍生的前体相比,常规含氮前体(例如,聚(苯胺))不一定是可持续的和相对昂贵的。

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