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ACTIVATED CARBONS FROM PETROLEUM RESIDUES FOR METHANE STORAGE.

机译:来自石油残留物的活性炭用于甲烷储存。

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Due to its abundance, cheapness and clean burning characteristics, methane is an interesting alternative fuel. Compressed natural gas is being used in vehicles but its use involves high storage pressures (200bar). Adsorbed natural gas is an alternative that reduces this storage pressure to 35bar at ambient temperature. In order to be economically viable, methane adsorption, which is the major component of natural gas, should be higher than 150 volumes of storage gas per volume of adsorbent. This objective can be achieved by designing activated carbons with a tailored micropore size, between 8 and 11 .2 ?, with a narrow pore size distribution and an appropriate density [1, 2]. The use of petroleum residues as a precursor material has a great versatility when designing activated carbons with specific textural properties. The operation variables of the heat treatment as well as the kind of petroleum residue, determine the characteristics of the mesophase pitch and the activated carbons that can be produced [3, 4]. Thus, the main objective of this study is to reach a compromise between microporosity development and packing density to achieve the largest possible amount of methane storage, expressed per volume of absorbent.
机译:由于其丰富,廉价和清洁的燃烧特性,甲烷是一个有趣的替代燃料。压缩的天然气在车辆中使用,但其使用涉及高储存压力(200bar)。吸附的天然气是在环境温度下将该储存压力降低到35bar的替代方案。为了经济上可行,甲烷吸附,即天然气的主要成分,每体积的吸附剂应高于150体积的储存气体。该目的可以通过设计具有定制微孔尺寸的活性碳,在8到11.2之间,孔尺寸分布窄和适当的密度[1,2]来实现。当设计具有特异性纹理性质的活性碳时,使用石油残留物作为前体材料具有很大的通用性。热处理的操作变量以及石油残留物的种类确定了中间相沥青的特性和可以产生的活性碳[3,4]。因此,本研究的主要目的是在微孔发育和填充密度之间达到折衷以达到每体积吸收剂表达的最大可能量的甲烷储存量。

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