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Modelling the microstructural development of graphite during oxidation

机译:氧化过程中石墨的微观结构发展建模

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The solid state kinetic approach has been successfully applied to various gas-solid reactions. Invariably such a kinetic expression contains a conversion function. In the absence of mass transfer or other interfacial limitations such a conversion function is representative of the microstructural development of the solid substrate as the reaction proceeds. In the past very little work has focused on determining this conversion function for the oxygen-graphite reaction. Remarkably the same may be said for the broader reaction of any generic carbon material with oxygen. This seems strange given the clear dependence of carbon reactivity on its microstructure and the development of this structure as oxidation takes place.
机译:固态动力学方法已成功应用于各种气体固体反应。总是这样的动力学表达包含转换功能。在没有传质或其他界面限制的情况下,这种转化函数代表固体基材的微观结构显影,因为反应进行。在过去非常几乎没有重点研究氧气 - 石墨反应的这种转化功能。对于任何通用碳材料与氧的更广泛的反应,可以说是相同的。考虑到碳反应性对其微观结构的明显依赖性以及作为氧化的这种结构的发展,这似乎很奇怪。

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