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Interatomic force constant of AII BIV C2V and AI BIII C2VI optoelectronic materials

机译:AII BIV C2V和AI BIII C2VI光电材料的外部部力常数

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Interatomic force constant ($alpha@) of the A-C and B-C bonds in A$+II$/B$+IV$/C$-2$/$+V$/ and A$+I$/B$+III$/C$- 2$/$+VI$/ groups of optoelectronic materials has been calculated using plasma oscillations theory of solids. A new relation between force constant and plasmon energy has been obtained. The effect of delocalization of noble metal d- electrons has been taken into account while calculating the force constant of the A-C bond in A$+I$/B$+III$/C$-2$/$+VI$/ semiconductors. On the basis of the best-fit data, another simple equation has been proposed for the calculation of the force constant from their plasmon energy. The calculated values of force constant from these equations have been compared with the values reported by different workers. An excellent agreement has been obtained between them.
机译:交流和BC债券的跨剖视力常数($ alpha @)以$ + II $ / b $ + iv $ / c $ -2 $ / $ + v $ /和$ + i $ / b $ + III $ / c $ - 2 $ / $ + vi $ / vi $ /组的光电材料已经使用等离子体振荡理论计算了固体的理论。已经获得了力常数和等离子体能量之间的新关系。已经考虑了贵金属D-电子的临床化的影响,同时计算A-C键的力常数以$ + I $ + II $ + II $ + I $ / C $ -2 $ / $ + VI $ /半导体。在最佳拟合数据的基础上,已经提出了另一种简单的等式来计算从其等离子体能量的力常数。将来自这些方程的力常数的计算值与不同工人报告的值进行了比较。他们之间获得了很好的协议。

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