The dry reforming of methance with carbon dioxide has been studies over a Ni-based electrode-catalyst in a solid oxide membrane reactor under open-and closed-circult conditions. The effects of oxygen flux, reaction temperature, and feed concentration of performance of dry reforming of methance with carbon dioxide reaction have been investigated. Experiments were conducted using a solid oxide electrochemical membrane reactor consisting of an yittria stabilized zirconia (YSZ) disk as solid electrolyte with thin films of Ni-YSZ as the anode and La0.79Sr-0.16Mn0.8Co0.2O3 as the cathode. Also experiments were conducted over temperature ranges of 700-900oC and carbon dioxide/methane ratios of 0.5-2. During the reaction on Ni-based catalyst under open circuit condition, carbonaceous deposition took place, and resulted in unexpected decreases of reaction rates. Under closed-circuit conditions, passing anodic current which is electrochemically pumping of oxygen to the Ni-based electrode catalst, resulted in increases of methane reforming reaction rates and changes of product distributions. These were a reversible effects. Also carbonaceous deposition on Ni-based electrode was suppressed by acidic oxygen ion species (O2-, O-, O2-etc) electrochemically pumpoed to the anode.
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机译:用二氧化碳的甲基γ的干燥重整已经在固体氧化物膜反应器中的基于Ni基电极催化剂的研究,在开放和闭合条件下。研究了氧气通量,反应温度和饲料浓度的效果,对二氧化碳反应进行干燥性能的性能的性能。使用由yittra稳定的氧化锆(YSZ)盘组成的固体氧化物电化学膜反应器进行实验,作为固体电解质,其具有Ni-YSZ的薄膜作为阳极和La0.79SR-0.16mN0.8Co0.2O3作为阴极。还在700-900oC的温度范围和0.5-2的二氧化碳/甲烷比的温度范围内进行实验。在开路条件下对Ni基催化剂的反应期间,发生碳质沉积,并导致反应速率的意外降低。在闭环条件下,将阳极电流通过电化学泵送到Ni基电极催化,导致甲烷重整反应速率的增加和产品分布的变化。这些是可逆的效果。通过酸性氧离子物质(O 2 - ,O 2 O 2 -ET)抑制了Ni基电极上的碳质沉积。电化学泵送到阳极。
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