Magnetic transitions in manganese benzoquinone coordination polymers

摘要

Coordination polymers exhibiting magnetic properties can be considered as promising materials for magnetic applications. We obtained such materials by means pf mechanochemical incorporation of binuclear metal complexes Mn-O-Mn into polystyrene. Incorporation of binuclear manganese complexes was achieved by using substituted benzoquinones (organic acceptors) as intermediate ligands that react with manganese acetylacetonate and provide new coordination and stabilization of manganese in different valence states. Magnetic transitions in this system are due to reversible disproportionation process Mn~(3+)-O-Mn~(3+)<=>Mn~(2+)-O-Mn~(4+) in the binuclear complex. The structure of the binuclear complex was obtained using ab initio calculations.