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Sol-gel-derived thick coatings and their thermomechanical and optical properties

机译:溶胶 - 凝胶衍生的厚涂层及其热机械和光学性质

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摘要

The preparation of crackfree and transparent SiO$-2$/ coatings on soda lime glass with thicknesses of about 8 $mu@m after densification at 500$DGR@C is presented. The high thickness can be obtained by using an 80:20 mixture of methyltriethoxysilane and tetraethyl orthosilicate as alkoxide precursors in combination with an aqueous colloidal SiO$-2$/ sol with particle sizes of about 7 nm. This principle of synthesis is also applied to ZrO$-2$/ containing coatings yielding to thicknesses of about 3 $mu@m. Refractive index measurements indicate that the coatings are nearly completely densified. At higher temperatures tensile stresses appear within the layers and are transmitted to the substrate, increasing its thermal stability.
机译:在500美元DGR @ C致密化后,在苏打石灰玻璃上制备粗糙和透明SIO $ -2 $ /涂层厚度约为8美元@ M。通过使用80:20的甲基三乙氧基硅烷和作为醇硅酸盐的混合物作为醇氧化物前体的含水胶体SiO $ -2 $ /溶胶,粒度为约7nm的粒度。这种合成原则也适用于ZrO $ -2 $ /含有涂层,含有约3 $ MU @ M的厚度。折射率测量表明涂层几乎完全致密化。在较高的温度下,拉伸应力出现在层内,并传递到基板,增加其热稳定性。

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