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High Temperature Oxidation and Wear Resistance of Y-modified Hot Dipping Aluminized Coating on SCH12 Steel

机译:SCH12钢上Y改性热浸镀铝层的高温氧化和耐磨性

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Microstructures, high-temperature oxidation and wear resistance of hot dipping Al-Si-Y coating on SCH12 heat resistant cast steel were investigated in this study. The aluminized coating was characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction (XRD). The results showed that the coating was composed of the Al-rich outer layer and the intermetallics inner layer. In the Al-rich layer, some Y-rich precipitates and Fe-Al-Si-Cr precipitates could be observed. The intermetallics layer presented three layers induced by the increase of Fe, Cr, Ni content and the corresponding decrease of Al, Si content. The oxidation tests were conducted in still air at 850 °C for up to 100 h. After oxidation, a top oxide scale composed of mainly a-AI2O3, AI5Y3O12 was formed on the steel surface. The intermetallics beneath the oxide scale consisted of mainly FeAl and small amount of Fe2Al5 and Cr3Si phase. The mass gain of the coated and uncoated SCHlsteel is 0.45 mg/cm2 and 0.57 mg/cm2, respectively. The wear resistance was investigated using a high-temperature pin-on-disc tribometer at 650 °C. The wear rate for the coated and uncoated steel is 0.45 μmVμm-N and 3.01 μm3/μm-N, respectively. The high temperature wear tests and oxidation tests results demonstrated that the yttrium-modified aluminized specimen had significantly improved high-temperature wear resistance and equivalent oxidation resistance compared with the original SCH12 specimen.
机译:研究了SCH12耐热铸钢上热浸Al-Si-Y涂层的组织,高温氧化性能和耐磨性。通过扫描电子显微镜(SEM),能量色散X射线光谱法(EDX)和X射线衍射(XRD)表征镀铝涂层。结果表明,涂​​层由富铝外层和金属间化合物内层组成。在富铝层中,可以观察到一些富Y析出物和Fe-Al-Si-Cr析出物。 Fe,Cr,Ni含量的增加和Al,Si含量的相应减少导致金属间化合物层出现三层。氧化测试在850°C的静止空气中进行长达100小时。氧化后,在钢表面形成了主要由α-Al2O3,Al5Y3O12组成的顶部氧化皮。氧化皮下的金属间化合物主要由FeAl和少量的Fe2Al5和Cr3Si相组成。涂覆和未涂覆的SCHlsteel的质量增益分别为0.45 mg / cm2和0.57 mg / cm2。使用高温针盘式摩擦计在650°C下研究了耐磨性。涂层钢和未涂层钢的磨损率分别为0.45μmVμm-N和3.01μm3/μm-N。高温磨损试验和氧化试验结果表明,与原始SCH12试样相比,钇改性的渗铝试样具有显着改善的高温耐磨性和等效的抗氧化性。

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