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Design and optimization of broadband and transparent SERS based on transformation optics

机译:基于变换光学的宽带透明SERS设计与优化

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In this work, a novel transparent surface-enhanced Raman scattering (SERS) for the application of probe sensing ispresented. This SERS is made by a two-dimensional array of noble metal which contains nano bowls with scatterednanospheres on its surface. Using the theory of transformation optics, we show that the curvature of nano bowlsamplify the electric field around the nanospheres. This amplification is broadband due to the inherent nature of spacetransformation which does not rely on frequency. Comparisons with conventional flat SERS are done to demonstrate theadvantages of the present design. We show that the curvature of these nano bowls increases the volume of the hotspot byone order of magnitude. This significantly reduces the response time of the SERS. Also, it is shown that this curvatureamplifies the electric field in hotspot more than hundreds of times greater than SERS without using those nano bowls.The calculated amplification of the Raman signal is more than one billion times so this surface is a promising candidatefor single molecule detection. The optimization and simulations are done using the Finite Element numerical algorithm.
机译:在这项工作中,一种新颖的透明表面增强拉曼散射(SERS)用于探针传感的应用是 提出了。此SERS由包含贵金属的二维阵列组成,其中包含分散的纳米碗 表面上的纳米球。利用变换光学理论,我们证明了纳米碗的曲率 放大纳米球周围的电场。由于空间的固有性质,这种放大是宽带的 不依赖频率的变换。与传统的平面SERS进行了比较,以证明 本设计的优点。我们表明,这些纳米碗的曲率增加了热点的体积, 一个数量级。这大大减少了SERS的响应时间。而且,表明该曲率 不使用那些纳米碗,可以将热点中的电场放大到数百倍,比SERS大。 计算得出的拉曼信号放大率超过十亿倍,因此该表面是一个有前途的候选对象 用于单分子检测。优化和仿真是使用有限元数值算法完成的。

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