Fabrication of self-assembled nanoparticle cluster array using surface affinity difference of isotropic droplets in nematic medium

摘要

We demonstrated a novel nanoparticle (NP) self-assembly method in a liquid crystal (LC) medium by exploiting twophysical phenomena: (i) surface affinity contrast of isotropic pockets in nematic phase for ITO and self-assembledmonolayer (SAM), and (ii) NP solubility contrast in isotropic and nematic phase. In the former phenomenon, the highermolecular roughness of ITO surface than SAM surface induced the higher surface affinity of isotropic pockets on theITO surface. Hence, the isotropic pockets were anchored on the ITO islands of the patterned ITO substrate, while thenematic medium remained on the other area in which SAM was created. In the latter phenomenon, the uni-directionalalignment in the bulk LC of nematic phase was mismatched with the one on the NP interface while the isotropic phasedid not show any mismatch between the LC alignment in bulk and at the NP interface. The alignment mismatch innematic phase resulted in the poorer NP solubility than it in isotropic phase. Hence, this large NP solubility contrast intwo phases resulted in the NPs were confined to the isotropic pockets and dragged by the phase-boundary. By combiningthe two phenomena, we successfully fabricated the self-assembled NP cluster array on the ITO islands of the patternedITO substrate. Since no electric or magnetic field is used in this method, it is applicable to a wide variety of NPsincluding ferroelectric, ferromagnetic etc. This method can potentially be utilized for fabrication of photonic crystals.