We measure and simulate the diffuse scattering return from sparse particles of RDX, caffeine, and acetaminophendeposited on substrates consisting of smooth aluminum, silicon, and glass substrates at a distance of 3.6 musing a mid-infrared supercontinuum FTIR sensor. The measured spectra show that molecular fingerprintregime contains reectance peaks that can be used for chemical identiffication and the mid-wave infrared providesinformation for target orientation. Furthermore, we demonstrate that spectra obtained using our supercontinuumFTIR sensor can be accurately simulated using a Bobbert-Vlieger model. The Bobbert-Vlieger model can thenbe used to create a library that can account for the trace chemical, underlying substrate, and target orientation,for stand-off chemical identication.
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