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Sol-gel broadband antireflective and scratch-resistant coating for megajoule-class laser amplifier blastshields

机译:兆焦级激光放大器防爆罩的溶胶-凝胶宽带抗反射和耐刮擦涂层

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Abstract: A novel optical coating developed to reduction of specular reflection has been developed using the sol-gel route. The sol-gel antireflective (AR) coating is made from tantalum and silicon oxide-based solutions. First layer is deposited from a solution based on polymeric tantalum oxide. Second layer is containing silica polymeric matrix in order to get a double-layer optical stack. Sol-gel synthesis have been carried out starting from cheap precursors in order to produce metallic alkoxide-based solution, each one suitable for liquid-deposition technique use such as dip-coating. After layer deposition, a curing step is required. Both thermal and UV-curing could induce layer densification and generate final coating properties. Thermal baking step does not exceed 150 degrees C temperature. This two-layer antireflective coating has been optimized to offer scratch- resistance allowing easy-cleaning and also broadband anti- reflection property onto various substrate. Experiments of AR-coating deposition onto large-area high-power laser glass plates is described. Based on calculations, the amplification yield using such a sol-gel coating onto LMJ- blastshields is evaluated to be ca. 7 percent. !4
机译:摘要:已经开发出一种新型的光学镀膜,旨在减少镜面反射。溶胶-凝胶抗反射(AR)涂层由钽和氧化硅基溶液制成。从基于聚合钽氧化物的溶液中沉积第一层。第二层包含二氧化硅聚合物基体,以获得双层光学叠层。为了生产基于金属醇盐的溶液,从廉价的前体开始进行溶胶-凝胶合成,每种溶液均适用于液体沉积技术,例如浸涂。在层沉积之后,需要固化步骤。热固化和紫外线固化均可引起层致密化并产生最终的涂层性能。热烘烤步骤的温度不超过150摄氏度。该两层抗反射涂层已经过优化,可提供耐刮擦性,易于清洁,并且在各种基材上均具有宽带抗反射特性。描述了在大面积高功率激光玻璃板上进行增透膜沉积的实验。基于计算,使用在LMJ-blastshields上的这种溶胶-凝胶涂层的扩增产率估计为约。百分之七!4

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