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Nanocomposites: Manufacturing, Microstructural Characterization and Mechanical Testing

机译:纳米复合材料:制造,微结构表征和机械测试

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Carbon Nanotubes (CNT) offer exceptional thermal, electrical and mechanicalproperties. While an increase in thermal and electrical conductivity can be readilyachieved by addition of CNT to a polymer base, the subsequent effect onmechanical properties must be investigated. In this study, nanocomposite sampleswere manufactured using injection molding process. Multiwall Carbon Nanotube(MWCNT) masterbatch with 15 wt.% MWCNT concentrations were diluted withPA 6/6 pellets to create five different CNT concentration ranging from 3 wt.% in 3wt.% increments. The neat polymer sample was also manufactured as a controlspecimen. Mechanical properties such as Young’s modulus, Tensile strength andelongations were determined to see the effect of CNT content on overall properties.Scanning Electron Microscopy (SEM) images were used to evaluate the uniformdistribution of CNT in the polymer phase. The results showed that the stiffnessincreased as the CNT content increased, however, the increase in strength reached athreshold value around 6 wt.% beyond which the strength decreased. It wasobserved that the elongation decreased significantly by addition of CNT into thepolymer. The elongation dropped from an average of 190% for the neat sample to5% for 15 wt.% CNT content sample. Such decrease in elongation might render thepolymer unsuitable for the application it has been designed for. The findings of thisstudy show that improving thermal and electrical properties of polymers does notcome without a sacrifice on mechanical properties.
机译:碳纳米管(CNT)提供出色的热,电和机械性能 特性。虽然可以很容易地提高导热性和导电性 通过将CNT添加到聚合物基料中来实现 机械性能必须进行调查。在这项研究中,纳米复合材料样品 使用注射成型工艺制造。多壁碳纳米管 MWCNT浓度为15 wt。%的(MWCNT)母料用 PA 6/6颗粒可产生五种不同的CNT浓度,范围从3 wt。%到3 wt。%增量。还制备了纯净的聚合物样品作为对照 样品。机械性能,例如杨氏模量,拉伸强度和 确定伸长率以观察CNT含量对整体性能的影响。 扫描电子显微镜(SEM)图像用于评估均匀性 CNT在聚合物相中的分布。结果表明,刚度 随着CNT含量的增加而增加,但是,强度的增加达到了 阈值约为6 wt。%,超过此阈值强度会降低。它是 观察到通过向碳纳米管中添加CNT可以显着降低伸长率 聚合物。伸长率从纯样品的平均190%下降到 对于15 wt。%的CNT含量样品为5%。伸长率的这种降低可能会导致 不适合其设计用途的聚合物。这个的发现 研究表明,改善聚合物的热和电性能不会 无需牺牲机械性能。

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