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Accelerated corrosion tests for marine paint systems used for ship's topsides and superstructures

机译:船舶顶部和上层建筑用船舶油漆系统的加速腐蚀测试

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Accelerated corrosion tests including the neutral salt spray test ISO 9227 or cyclic corrosion tests (ISO 20340-Annex A or NACE SP0108) are conducted to assess the performance of marine paints. Several studies sponsored by the French Navy have been conducted during the last 5 years aiming to develop more reliable testing conditions. The unreliability of the neutral salt spray test to mimic field exposures was demonstrated, implying that this test should not be used for prediction. On the contrary, a satisfying correlation to atmospheric field exposure on a ship in service was observed using a 6 months cyclic test from the automotive industry (e.g. Volvo STD23-0014) with a deviation inferior to 25% and an acceleration factor of 4. In view of optimizing testing conditions, a large project name Corrosion Control of Navy Ship was initiated in 2013. One task aimed at shortening the test duration by increasing the acceleration factor of the test without losing correlation to field. Thus, a design of experiment was used to study key parameters such as NaCl concentration, the mode of application and frequency and the temperature. Ten different marine paint systems used for shipbuilding were selected. The results indicated an enhancement of the aggressiveness of the test when doubling the salt concentration from 1 to 2wt%, increasing the number of salt spray per week (from 2 to 3) and the temperature from 35 to 45°C while keeping a rather satisfying correlation to field exposure.
机译:进行了加速腐蚀试验,包括中性盐雾试验ISO 9227或循环腐蚀试验(ISO 20340-Annex A或NACE SP0108),以评估船用涂料的性能。在过去的5年中,法国海军发起了数项研究,旨在开发更可靠的测试条件。证明了中性盐雾试验不适合模拟野外暴露,这表明该试验不应用于预测。相反,使用汽车行业进行的为期6个月的循环测试(例如,沃尔沃STD23-0014)观察到与在役船舶上的大气场暴露具有令人满意的相关性,其偏差小于25%,加速系数为4。考虑到优化测试条件,于2013年启动了一个大型项目“海军舰船腐蚀控制”。一项任务旨在通过增加测试的加速因子而又不失去与现场的相关性,从而缩短测试时间。因此,通过实验设计来研究关键参数,例如NaCl浓度,施用方式,频率和温度。选择了十种用于造船的船用油漆系统。结果表明,当将盐浓度从1%增至2wt%时,测试的侵略性增强;每周喷盐次数(从2增至3);温度从35增至45°C,同时保持了令人满意的水平与野外接触的相关性。

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