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Micro-galvanic Corrosion of Cu-Ru Couple in Potassium Periodate (KIO4) Solution

机译:高碘酸钾(KIO4)溶液中铜-钌对的微电腐蚀

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During chemical mechanical polishing step in ultra-large integrated circuit manufacturing process, galvanic corrosion may happen between the directly connected Cu and Ru parts. This problem is much severe when the polishing slurry contains KIO4 as the oxidant. This micro-galvanic corrosion could cause surface non-uniformity and defects, such as aggravated Cu dishing and pitting. To clarify the mechanism of the micro-galvanic corrosion, model Cu-Ru samples, with a small Cu disc embeded in a large Ru disc, were prepared and used for investigation of the galvanic corrosion during the exposure to 0.015 M alkaline KIO_4 solutions.
机译:在超大型集成电路制造过程中的化学机械抛光步骤中,直接连接的Cu和Ru零件之间可能会发生电化腐蚀。当抛光浆料包含KIO 4作为氧化剂时,该问题非常严重。这种微电腐蚀会导致表面不均匀和缺陷,例如加剧的铜凹陷和点蚀。为了阐明微电偶腐蚀的机理,制备了在小Ru盘中嵌入小Cu盘的模型Cu-Ru样品,并将其用于研究暴露于0.015 M碱性KIO_4溶液中的电偶腐蚀。

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