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Mechanical and Thermo-Mechanical Behaviour of Aliphatic Polyketones in Wet Environments

机译:潮湿环境中脂肪族聚酮的机械和热机械行为

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Aliphatic polyketones are a rediscovered polymer family of highly polar thermoplastic engineering polymers of high crystallinity. Due to their chemical structure they show an interesting combination of materials behaviour. Mechanically loaded polyketones exhibit good modulus and strength values paired with high deformability and energy absorption. Polyketones show a low creep tendency, especially fibre-reinforced types, and good wear and friction properties. They feature an excellent chemical resistance, especially against hydrolysis and low moisture absorption with low swelling in water. Furthermore polyketones show good gas barrier properties. Due to the technical profile and the easy and energy efficient processing polyketones may be considered as interesting alternative materials for water as well as electronic and structural components. Regarding these possible application fields polyketones have to be analysed regarding the impacts of water absorption and elevated temperatures and have to be compared with polymeric materials actually used in these fields, e.g. Polyamide 12. Respecting wet environments at elevated temperatures a testing route was defined to evaluate the suitability of polyketones in wet environments compared to engineering polymers actually used in these applications. In this work the mechanical and thermo-mechanical behaviour of aliphatic polyketones compared to Polyamide 12 is investigated, considering the influence of water, temperature and a combination of both impacts, extending the knowledge of the behaviour of polyketones.
机译:脂肪族聚酮是重新抵抗的聚合物系列高结晶度的高极性热塑性工程聚合物。由于它们的化学结构,它们显示了一种有趣的材料行为组合。机械装载的聚酮具有高可变形性和能量吸收的良好模量和强度值。聚酮显示出低蠕变倾向,尤其是纤维增强类型,良好的磨损和摩擦性能。它们具有优异的耐化学性,尤其是抗水解和低水力吸收,在水中低膨胀。此外,聚酮显示出良好的阻气性。由于技术简介,简单和节能的加工多酮可以被认为是水的有趣的替代材料以及电子和结构部件。关于这些可能的应用领域必须分析有关吸水和升高的温度的影响,并且必须与实际用于这些领域的聚合物材料进行比较,例如,聚酰胺12.升高温度的潮湿环境定义了测试路线,以评估与这些应用中实际使用的工程聚合物相比的湿环境中聚酮在潮湿环境中的适用性。在这项工作中,考虑到水,温度和两种冲击的组合,延长了多酮的影响,研究了与聚酰胺12相比的脂族聚丙酮的机械和热力学行为。

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