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ALIPHATIC POLYKETONE RESIN COMPOSITION AND ALIPHATIC POLYKETONE RESIN MOLDED ARTICLE

机译:脂肪族聚酮树脂组合物和脂肪族聚酮树脂模塑制品

摘要

PROBLEM TO BE SOLVED: To obtain a compsn. giving a molded article with no shape change owing to washing, drying, heat treatment, etc., and with an excellent mechanical performance at a low temp. by including both an aliphatic polyketone resin and a liquid crystalline polymer. ;SOLUTION: A resin compsn. contains 100 pts.wt. of an aliphatic polyketone resin of a polymer having a repeating unit expressed by the formula and 5-100 pts.wt. of a liquid crystalline polymer. The polyketone resin has pref. an m.p. of 175-300°C, and a limiting viscosity number (measured at 60°C in m-cresol) of 0.5-10 dl/g, and comprises an alternating copolymer of carbon monoxide with an ethylenically unsatd. hydrocarbon compd. selected from propene, 1- butene, etc., being a semicrystalline aliphatic resin. The liquid crystalline polymer is pref. a thermotropic liquid crystalline polyester which indicates a liquid crystallinity on melting. A melt viscosity ratio of the polyketone resin/the liquid crystalline polymer is pref. 1.1-20.0. In the formula, G is a 3C or more group; m and n are each a positive integer, but m/(m+n) is 0.5 or less.;COPYRIGHT: (C)1999,JPO
机译:要解决的问题:获得compsn。成型品不会因洗涤,干燥,热处理等而发生形状变化,并且在低温下具有优异的机械性能。通过同时包括脂族聚酮树脂和液晶聚合物。 ;解决方案:树脂成分。包含100pts.wt。具有由下式表示的重复单元和5-100pts.wt的聚合物的脂族聚酮树脂的制备。液晶聚合物。聚酮树脂具有优选。每分钟粘度为175-300℃,极限粘度值为0.5-10dl / g(在60℃下,在间甲酚中测得),并且包含一氧化碳和烯键式不饱和的交替共聚物。碳氢化合物选自丙烯,1-丁烯等的半结晶脂族树脂。液晶聚合物是优选的。一种热致液晶聚酯,在熔融时具有液晶性。聚酮树脂/液晶聚合物的熔融粘度比为优选。 1.1-20.0。式中,G为3C以上的基团。 m和n均为正整数,但m /(m + n)等于或小于0.5 .;版权:(C)1999,JPO

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