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TRIBOCORROSION STUDIES ON SURFACE MODIFIED MEDICAL GRADE STAINLESS STEEL

机译:表面改性医用级不锈钢的三元腐蚀研究

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Tribocorrosion performance of medical grade AISI 316L stainless steel with and without surface modification has been studied during exposure to an electrolyte. Some of the samples investigated were surface modified by plasma nitriding (at both 400 and 550 °C), and others by a special arc physical vapor deposition to secure a thin layer of a diamond-like carbon (DLC) coating on the surface of the samples. XRD and SEM were used to characterize the homogeneity and microstructure of all samples. Potentiodynamic polarization measurement and tribocorrosion tests were performed multiple times on all groups of samples. It was established that surface treated SS 316L exhibited totally different passive behaviors, which consequently lead different tribocorrosion performance in the electrolyte. It was also established that the DLC coating performed as a solid lubricant in the ball-on-plate tests, and the resulting wear track after the tribocorrosion tests was almost negligible. On the other hand, the untreated and Nitriding 400 °C samples experienced wear accelerated corrosion due to their passive behavior. The results suggest that the DLC coated SS 316L have the best performance at the combined wear and corrosion environment, while the untreated and Nitriding 400 °C samples should be avoided to apply in biological tribocorrosion conditions.
机译:在暴露于电解质期间,对具有和不具有表面改性的医用级AISI 316L不锈钢的摩擦腐蚀性能进行了研究。所研究的一些样品通过等离子渗氮(分别在400和550°C下)进行了表面改性,而另一些样品则通过特殊的电弧物理气相沉积进行了表面改性,以确保在金刚石表面上形成一层类金刚石碳(DLC)涂层的薄层。样品。 XRD和SEM用于表征所有样品的均质性和微观结构。对所有样品组进行了多次动力极化测量和摩擦腐蚀试验。已经确定,表面处理过的SS 316L表现出完全不同的钝化行为,因此在电解液中导致了不同的摩擦腐蚀性能。还确定了DLC涂层在板球测试中作为固体润滑剂发挥作用,并且在摩擦腐蚀测试后产生的磨损痕迹几乎可以忽略不计。另一方面,未经处理和渗氮的400°C样品由于其被动行为而遭受磨损加速腐蚀。结果表明,经DLC涂层的SS 316L在磨损和腐蚀的综合环境中具有最佳性能,而应避免将未经处理和渗氮的400°C样品应用于生物摩擦腐蚀条件。

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