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THE RELATIONSHIP BETWEEN SURFACE ROUGHNESS AND CORROSION

机译:表面粗糙度与腐蚀之间的关系

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There are different parameters which can affect electrochemical reactions such as type of electrolyte, velocity, temperature, oxidizing agents, impurities, anode material type and surface treatment. It has been shown that pre-treatment of working electrode (anode) through abrasion techniques is one of the most important parameters affecting on Tafel slopes and consequently corrosion rate. Surface roughness of the metal surface is a major influence on general corrosion, nucleation of metastable pitting and pitting potential as well. In this study different surface roughnesses were created on nickel surface by SiC papers and corrosion properties were compared. Electrochemical impedance spectroscopy (EIS) and profilometry tests were carried out on all the samples and the results were compared with another sample prepared through laser ablation method. Corrosion rate values were calculated and were compared with EIS results for all the samples and a trend in the effect of roughness on corrosion protection of nickel was introduced. SEM and 3D roughness images were taken and compared for all of the samples before and after corrosion tests. Different mechanisms were distinguished for samples created through different methods. The lower the roughness values, the more the corrosion resistance. Sample with patterns created through laser ablation method showed the best protection properties compared to other samples.
机译:有不同的参数会影响电化学反应,例如电解质的类型,速度,温度,氧化剂,杂质,阳极材料的类型和表面处理。已经表明,通过磨蚀技术对工作电极(阳极)进行预处理是影响Tafel斜率并因此影响腐蚀速率的最重要参数之一。金属表面的表面粗糙度是对一般腐蚀,亚稳点蚀成核和点蚀电位的主要影响。在这项研究中,SiC纸在镍表面产生了不同的表面粗糙度,并比较了其腐蚀性能。对所有样品进行了电化学阻抗谱(EIS)和轮廓测定法测试,并将结果与​​通过激光烧蚀法制备的另一样品进行了比较。计算了所有样品的腐蚀速率值,并将其与EIS结果进行了比较,并介绍了粗糙度对镍腐蚀防护作用的趋势。在腐蚀测试之前和之后,拍摄并比较了所有样品的SEM和3D粗糙度图像。对于通过不同方法创建的样本,区分了不同的机制。粗糙度值越低,耐腐蚀性越强。与其他样品相比,具有通过激光烧蚀方法创建的图案的样品显示出最佳的保护性能。

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