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Evaluation of test methods to assess lead release from brass to drinking water

机译:评估测试方法以评估铅从黄铜到饮用水中的释放

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Brass components are used for various drinking water related applications such astaps, fittings, valves, etc. Brass materials are commonly alloyed with 1-3 % lead,which acts as a lubricant during machining. However, problems with lead releasefrom brass installations to drinking water have been observed in households in Sweden,and since lead is highly toxic this may pose a threat to health. This article focuseson the different standard test methods for assessment of lead release from brassto drinking water.Three assessment methods were evaluated, representing the product tests in Scandinavia(NKB4) and US (ANSI/NSF-61:2010), and the European material test (EN15664:1-2). Furthermore the effect on lead release of chlorine washing of brass wasalso investigated. This washing is performed to remove the smeared lead layer onthe surface, originating from the machining operation.Eight materials with lead content from 0.14 to 3 weight-% were included in the study.The lead concentration in the exposure water was monitored over time and the materialswere then assessed according to the criteria specified in each standard.The study showed that results from the long-term test do not correlate with thosefrom the short term tests, indicating that different processes are involved, dependingon the operation time of the exposure. A clear tendency was observed, that lead releaseis highest and most fluctuant in the beginning of the operation time, while astabilization is observed after approximately 15-20 weeks. This pattern is observed inboth the washed and un-washed samples, indicating that corrosion processes areinvolved.The assessment of a material depends on the method and no material consistentlyfails or passes all three tests. Lead release is fluctuating dramatically during the firstweeks, resulting in low reproducibility of the Scandinavian NKB4 test.Washing of the smeared lead on the surface decreases lead release with approximately75 % in a short term test, while no positive effect is observed in a long termtest.In conclusion, the results of short term tests are highly influenced by the smearedlead on the surface of the material and cannot be used to predict the long term performanceof the material.
机译:黄铜部件用于各种与饮用水有关的应用,例如 水龙头,配件,阀门等。黄铜材料通常与1-3%的铅合金化, 在加工过程中用作润滑剂。但是,铅释放存在问题 在瑞典的家庭中,人们观察到从黄铜装置到饮用水的各种变化, 由于铅具有剧毒,因此可能对健康构成威胁。本文重点 评估黄铜中铅释放量的不同标准测试方法 喝水。 评估了三种评估方法,代表了斯堪的纳维亚半岛的产品测试 (NKB4)和美国(ANSI / NSF-61:2010),以及欧洲材料测试(EN 15664:1-2)。此外,黄铜洗氯对铅释放的影响是 还进行了调查。进行该洗涤以去除表面上的污迹化的铅层。 源自加工操作的表面。 研究中包括八种铅含量为0.14%至3%(重量)的材料。 随时间监测暴露水中的铅浓度,并对材料进行监测。 然后根据每个标准中指定的标准进行评估。 研究表明,长期测试的结果与那些结果不相关。 来自短期测试,表明涉及不同的过程,具体取决于 曝光时间观察到明显的趋势,即铅释放 在手术开始时最高且波动最大,而 在约15-20周后观察到稳定。这种模式在 清洗过的和未清洗过的样品都表明腐蚀过程是 涉及。 对材料的评估取决于方法,并且没有一致的材料 未通过或全部通过三个测试。铅释放在第一阶段波动很大 个星期,导致斯堪的纳维亚NKB4测试的重现性低。 表面上被污染的铅的清洗减少了铅的释放,大约降低了铅的释放量。 在短期测试中为75%,而在长期测试中则未观察到积极的效果 测试。 总之,短期测试的结果受涂片的影响很大 材料表面上的铅,不能用来预测长期性能 材料。

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