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Conversion of Industrially Processed Biomass Waste into Value-added Products Using High Temperature Agents

机译:使用高温介质将工业加工生物质废物转化为增值产品

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Biomass is renewable, widely distributed along the Earth resource which can be utilized for energy and chemicals generation, gradually replacing the significance of fossil fuels. In this work the conversion of an industrially processed biomass waste (straw pellets) has been studied by means of High Temperature Steam Gasification (HTSG) and High Temperature Pyrolysis (HTP). The aim of the work is to optimize the process for a specific application. The experiments have been carried out using a lab-scale, batch-type plug-flow reactor, at Royal Institute of Technology (KTH). The primary objectives are focused to estimate an influence of temperature and steam-to-fuel ratio (S/F) on the fuel-to-gas conversion as well as composition, yields and heating value of generated gas. The sample temperature, mass loss, gas composition, LHV and gas yield of producer gas vs. residence time are reported for three different agent temperatures in the range 700-950°C and three different levels of S/F including 0 which corresponds to HTP. The gas yield was 2-3 Nm~3/kg and the LHV ranged between 8-13MJ/Nm~3. The results show increasing reaction rate, hydrogen yield and reduction of tar with increasing agent temperature and S/F. At S/F=3.2 the reduction of CO and hydrocarbons is observed even at 850°C yielding amount of hydrogen by 100% up to 38% compared with S/F =1.875.
机译:生物质是可再生的,在地球资源中分布广泛,可用于能源和化学物质的生产,逐渐取代了化石燃料的重要性。在这项工作中,已经通过高温蒸汽气化(HTSG)和高温热解(HTP)研究了工业处理的生物质废物(秸秆颗粒)的转化。这项工作的目的是针对特定应用优化过程。实验是在皇家技术学院(KTH)使用实验室规模的间歇式活塞流反应器进行的。主要目标集中在估算温度和蒸汽/燃料比(S / F)对燃料-气体转化率以及所产生气体的成分,产率和热值的影响。报告了在700-950°C范围内的三种不同试剂温度和三种不同水平的S / F(包括0对应于HTP)的样品温度,质量损失,气体成分,LHV和生产气的产气量与停留时间的关系。 。气体产量为2-3 Nm〜3 / kg,LHV为8-13MJ / Nm〜3。结果表明,随着试剂温度和S / F的增加,反应速率,氢气产率和焦油含量降低。在S / F = 3.2时,与S / F = 1.875相比,即使在850℃下也观察到CO和碳氢化合物的减少,氢气的产生量从100%提高到38%。

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