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High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low Catalytic Metal Loadings

机译:具有超低催化金属负载的高性能等离子溅射燃料电池电极

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Ultra-low Pt content PEMFC electrodes have been manufactured using magnetron co-sputtering of carbon and platinum on a commercial E-Tek uncatalyzed gas diffusion layer in plasma fuel cell deposition devices. Pt loadings lower than 0.01 mg cm~(-2) have been realized. The Pt catalyst is dispersed as small clusters with size less than 2 run over a depth of 500 nm. PEMFC test with symmetric electrodes loaded with 0.01 mg cm~(-2) led to maximum reproducible power densities as high as 0.4 Wcm~(-2) with Nafion 212. Replacement of platinum by palladium using plasma sputtering methods was also realized by preparing MEAs composed of 0.01 mg_(Pd) cm~(-2) for the anode and 0.01 mg_(Pd) cm~(-2) + 0.001 mg_(Pt) cm~(-2) for the cathode and Nafion 212 membrane. Power density as high as 250 mW cm~(-2) were achieved at 80°C, which corresponds to a specific power density of 250 kW g_(Pt)~(-1).
机译:Pt含量超低的PEMFC电极是通过在等离子燃料电池沉积设备中的商用E-Tek未催化气体扩散层上利用碳和铂的磁控管共溅射法制造的。已经实现了低于0.01 mg cm〜(-2)的Pt负载。 Pt催化剂以小于2的小簇的形式分散在500 nm的深度上。使用对称电极加载0.01 mg cm〜(-2)的PEMFC测试导致使用Nafion 212的最大可重现功率密度高达0.4 Wcm〜(-2)。通过制备MEA还可实现通过等离子溅射法用钯代替铂由阳极的0.01 mg_(Pd)cm〜(-2)和阴极的0.01 mg_(Pd)cm〜(-2)+ 0.001 mg_(Pt)cm〜(-2)和Nafion 212膜组成。在80°C时达到了250 mW cm〜(-2)的功率密度,这对应于250 kW g_(Pt)〜(-1)的比功率密度。

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