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High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low Catalytic Metal Loadings

机译:具有超低催化金属载荷的高性能等离子体溅射燃料电池电极

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Ultra-low Pt content PEMFC electrodes have been manufactured using magnetron co-sputtering of carbon and platinum on a commercial E-Tek uncatalyzed gas diffusion layer in plasma fuel cell deposition devices. Pt loadings lower than 0.01 mg cm~(-2) have been realized. The Pt catalyst is dispersed as small clusters with size less than 2 nm over a depth of 500 nm. PEMFC test with symmetric electrodes loaded with 0.01 mg cm~(-2) led to maximum reproducible power densities as high as 0.4 Wcm~(-2) with Nafion 212. Replacement of platinum by palladium using plasma sputtering methods was also realized by preparing MEAs composed of 0.01 mgPd cm~(-2) for the anode and 0.01 mg_(Pd) cm~(-2) + 0.001 mg_(Pt) cm~(-2) for the cathode and Nafion 212 membrane. Power density as high as 250 mW cm~(-2) were achieved at 80°C, which corresponds to a specific power density of 250 kW g_(Pt)~(-1).
机译:已经在等离子体燃料电池沉积装置中的商业E-TEK Uncalyzated气体扩散层上使用磁控凝固和铂制造的超低Pt含量PEMFC电极。已经实现了低于0.01mg cm〜(-2)的Pt载荷。 Pt催化剂分散为小簇,尺寸小于2nm,深度为500nm。具有0.01mg cm〜(-2)的对称电极的PEMFC测试导致了高达0.4 Wcm〜(-2)的最大可再现电力密度,其中Nafion 212.使用等离子体溅射方法使用钯替代铂,也通过制备测量来实现为阴极和Nafion 212膜组成为阳极的0.01mgpd cm〜(-2)和0.01mg_(pd)cm〜(-2)+ 0.001 mg_(pt)cm〜(-2)。在80°C下实现高达250mW cm〜(2)的功率密度,其对应于250kW G_(PT)〜(-1)的特定功率密度。

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