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Gelator in-situ Modify PMMA

机译:凝胶器原位改性PMMA

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摘要

Gelator (G2-C12-G2) was synthesized successfully, the structure of which was confirmed by 1H-NMR and Mass spectra (MS). And G2-Ci2-G2 was used to modify PMMA by "in-situ" polymerization. The results of gel permeation chromatography(GPC) showed that Mn and Mw/Mn of the PMMA composite were barely influenced by the incorporation of gel. The results of dynamic mechanical analysis (DMA) showed that the modified PMMA had higher modulus, toughness and glass transition temperature (Tg) than pure PMMA. Furthermore the results of spectrophotometer showed that the transparency of modified PMMA was nearly the same as pure PMMA .
机译:成功合成了Gelator(G2-C12-G2),并通过1H-NMR和质谱(MS)证实了其结构。然后使用G2-Ci2-G2通过“原位”聚合来改性PMMA。凝胶渗透色谱法(GPC)的结果表明,PMMA复合材料的Mn和Mw / Mn几乎不受凝胶掺入的影响。动态力学分析(DMA)的结果表明,改性的PMMA具有比纯PMMA更高的模量,韧性和玻璃化转变温度(Tg)。分光光度计的结果表明,改性聚甲基丙烯酸甲酯的透明度与纯聚甲基丙烯酸甲酯几乎相同。

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