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Photochemical Synthesis of ZnS Nanosheet and Its Use in Photodegradation of Organic Pollutants

机译:ZnS纳米片的光化学合成及其在有机污染物的光降解中的应用

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ZnS is an important photocatalyst and its use in photodegradation of organic pollutants may be effectively facilitated by developing new fabrication methods at room temperature and exploring novel new morphologies. In this paper, taking Na2S2O3 and ZnSO4 as the precursors, an 8 W 254nm UV lamp as the light source, ZnS nanosheet at the air-water interface was obtained by a photochemical route. X-ray diffraction, scanning electron microscopy were used to characterize the products. In addition, this material possessed excellent photocatalytic activities in photodegradation of some organic pollutants, for example methyl orange. Under the irradiation of a 300 W high-pressure mercury lamp, 0.02 g sample exhibits degradation efficiency 70% of 200ml 57;10-5M methyl orange in 60 min. This route is convenient, low-cost, green and can be extended to prepare other oxide or sulfide semiconductor nanostructures with photocatalytic activities.
机译:ZnS是一种重要的光催化剂,在室温下开发新的制备方法并探索新的形态可以有效地促进其在有机污染物的光降解中的应用。以Na2S2O3和ZnSO4为前驱体,通过光化学途径获得了8 W 254nm紫外灯为光源,在空气-水界面处获得了ZnS纳米片。 X射线衍射,扫描电子显微镜用于表征产物。此外,这种材料在降解某些有机污染物(例如甲基橙)方面具有出色的光催化活性。在300 W高压汞灯的照射下,0.02 g样品的降解效率为200ml 5的70%5 7; 10-5M甲基橙在60分钟内。该途径是方便,低成本,绿色的,并且可以扩展以制备具有光催化活性的其他氧化物或硫化物半导体纳米结构。

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