首页> 外文会议>2010 International Symposium on Next-Generation Electronics >Enhanced exciton-phonon efficiency in photoluminescence of SrTiO3 :Er films covered on ZnO nanorods
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Enhanced exciton-phonon efficiency in photoluminescence of SrTiO3 :Er films covered on ZnO nanorods

机译:ZnO纳米棒覆盖的SrTiO 3 :Er薄膜的光致发光中激子-声子效率的提高

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Characteristics of light emission of Er-doped SrTiO3 (STO) thin films (STO : Er) deposited on different surface morphologies by a sputtering technique were investigated. The luminescence efficiency of Er-doped STO films covered on ZnO nanorods was greater than deposited directly on Si (100) substrates in all specimens. Formation of one-dimensional well-aligned ZnO nanorods has been achieved using a simple aqueous solution method at low temperatures. The dependence of luminescence efficiency on Er3+ concentrations and annealing temperatures in the Er-doped STO films is governed by crystallinity and ion-ion interaction. The photoluminescence (PL) measurement of the Er-doped STO films covered on ZnO nanorods show that the much stronger intensity of green light is observed at annealing temperature 700 °C and 3 mol% Er3+ -doped concentration. The presence of clusters as the Er concentration exceed 3 mol% will diminish the emission intensity. Besides, concentration quenching was observed on STO films containing 5 mol% Er dopant. The phenomenon was attributed to energy transference and cross relaxation between closely sited Er3+ ions in the STO lattice. We also showed that the quenching mechanism of the luminescent intensity is evidently relational with Er-doped concentrations and annealing temperatures. The photoluminescence properties suggest that adding a 3 mol% Er-doped STO films covered on ZnO nanorods is the optimal choice for optoelectronic device applications.
机译:研究了通过溅射技术沉积在不同表面形貌上的掺Er SrTiO 3 (STO)薄膜(STO:Er)的发光特性。在所有样品中,覆盖在ZnO纳米棒上的掺Er的STO薄膜的发光效率均大于直接沉积在Si(100)衬底上的发光效率。使用简单的水溶液方法在低温下已经实现了一维良好排列的ZnO纳米棒的形成。掺STO薄膜中发光效率对Er 3 + 浓度和退火温度的依赖性取决于结晶度和离子-离子相互作用。 ZnO纳米棒上覆盖的掺Er STO薄膜的光致发光(PL)测量表明,在退火温度700°C和掺有3 mol%Er 3 + 的情况下,观察到的绿光强度要强得多。专注。当Er浓度超过3mol%时,团簇的存在将降低发射强度。此外,在含有5mol%Er掺杂剂的STO膜上观察到浓度猝灭。该现象归因于STO晶格中位置紧靠的Er 3 + 离子之间的能量转移和交叉弛豫。我们还表明,发光强度的猝灭机理显然与掺Er的浓度和退火温度有关。光致发光特性表明,添加覆盖在ZnO纳米棒上的3 mol%掺Er的STO膜是光电器件应用的最佳选择。

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