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ELECTROCHEMICAL METHODS FOR REPASSIVATION POTENTIAL MEASUREMENTS

机译:电化学电势势能测量方法

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The susceptibility of Alloy 22 (N06022) to crevice corrosion may depend on environmental and metallurgical variables and it was mostly tested to obtain crevice repassivation potentials. Regardless of all the combinations or variations of the electrochemical test methods Cyclic Potentiodynamic Polarization (CPP), Tsujikawa - Hisamatsu Electrochemical (THE), Potentiostatic (POT), and Mixed Poentiodynamic - Potentiostatic (PD - POT - PD), whenever crevice corrosion readily occurs, the values of repassivation potential for Alloy 22 seem comparable if all environmental and metallurgical variables remain the same. This finding suggests that the crevice repassivation potential is a property of the alloy in each testing condition and does not depend greatly on the manner it is obtained provided that highly aggressive conditions are used. Under less aggressive conditions, when crevice corrosion is more difficult to initiate, the value of repassivation potential may differ from method to method. In this work three different electrochemical methods (CPP, THE, and PD - POT - PD methods) were used to evaluate the susceptibility of Alloy 22 to crevice corrosion in two different solutions: one highly aggressive (1M NaCl at 90°C), and one weakly aggressive (1M NaCl + 0.15M NaNO_3 at 90 °C). The effect of applied torque was also investigated in these systems.
机译:合金22(N06022)对缝隙腐蚀的敏感性可能取决于环境和冶金变量,并且已对其进行大多数测试以获取缝隙再钝化电位。无论何时容易发生缝隙腐蚀,无论电化学测试方法的所有组合或变化如何,循环恒电位极化(CPP),Tsu川-久松电化学(THE),恒电位(POT)和混合恒动力-恒电位(PD-POT-PD) ,如果所有环境和冶金变量都保持不变,合金22的再钝化电位值似乎是可比的。这一发现表明,缝隙再钝化电位是合金在每种测试条件下的特性,并且在使用高侵蚀性条件的情况下,与获得的方式没有很大的关系。在侵蚀性较小的条件下,当缝隙腐蚀更难以引发时,重新钝化电位的值可能因方法而异。在这项工作中,使用三种不同的电化学方法(CPP,THE和PD-POT-PD方法)来评估22种合金在两种不同溶液中对缝隙腐蚀的敏感性:一种是高度侵蚀性的(在90°C下为1M NaCl),另一种是一种弱侵蚀性物质(在90°C下为1M NaCl + 0.15M NaNO_3)。在这些系统中还研究了施加扭矩的影响。

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