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Synthesis and High Dielectric Properties of Poly(aryl ether ketone)/Phthalocyanine

机译:聚(芳醚酮)/酞菁的合成及高介电性能

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@@High dielectric constant polymers with excellent electric properties, proper mechanical strength, and good processing properties are of great importance for applications such as super capacitors, on-chip capacitors, and electromechanical devices including artificial muscles, smart skins for drag reduction,and microelectromechanical systems. However, for one-component systems, it is hard to realize all these properties. Conventional polymers are easy to process but generally suffer from a low dielectric constant (less than 10). In the past several decades, the composite approach, in which high dielectric constant particulates (most of which are ferroelectric ceramics) were added to a polymer matrix, has been employed to raise the dielectric constant of polymer based materials. However, because ceramic materials have an elastic modulus much higher than that of polymers, the increased dielectric constant comes at the cost of losing flexibility and significant increase of the elastic modulus.
机译:@@具有优异的电性能,适当的机械强度和良好的加工性能的高介电常数聚合物对于超级电容器,片上电容器和包括人工肌肉,智能皮肤,用于减阻的智能皮肤和微机电的应用,具有重要的应用,以及微机电的应用非常重要系统。但是,对于一个组件系统,很难实现所有这些属性。常规聚合物易于处理,但通常遭受低介电常数(小于10)。在过去几十年中,已经采用了复合方法,其中将高介电常数(其中大部分是铁电陶瓷)加入聚合物基质中,以提高基于聚合物的材料的介电常数。然而,由于陶瓷材料具有远高于聚合物的弹性模量,所以增加的介电常数是损失柔韧性和弹性模量显着增加的成本。

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