Structure-controlled synthesis of novel soluble and thermally stable poly (aryl ether nitrile ether ketone ketone)/poly (aryl ether nitrile ether ketone biphenyl ketone) copolymers by electrophilic polycondensation

摘要

One new synthesis route was first designed to synthesize the biphenyl acid chloride (BPACl), and then a series of novel poly (aryl ether nitrile ether ketone ketone) (PENEKK)/poly (aryl ether nitrile ether ketone biphenyl ketone) (PENEKBK) copolymers with different controlled structure compositions were synthesized by electrophilic polycondensation and varying the molar ratio of BPACl to terephthaloyl chloride (TPC). The obtained PENEKK/PENEKBK copolymers were characterized by different physical and chemical techniques. The results showed, the copolymers with 10-50% molar contents of biphenyl moities exhibited good thermal properties with glass transition temperatures (T_gs) of 184-196℃, decomposition temperatures (T_ds) of 498-515℃, and good solubility in organic solvents (N-Methyl-2-pyrrolidone (NMP), N,N-dimethylformamide (DMF), and DMSO), indicating that they would have good potential for solvent processing. The thin films of the polymers had tensile strengths of 93.6-101.5MPa, Young's moduli of 3.03-3.32 GPa, elongations at break of 9-14%, indicating they were strong materials. The densities of the obtained polymers were 1.31-1.40 g/cm~(-3), which were far lower than those of some main inorganic materials (such as Fe, nearly 7.8 g/cm~(-3)), indicating that they would have possible potential for substituting some inorganic materials used as high temperature materials in some areas due to the merits of lightweight. Thus, the copolymers with 10-50% molar contents of biphenyl moities were promising polymer materials.