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The pH Dependence of Poly (acrylic acid)-graft-polypropylene Hollow Fiber Membrane

机译:聚丙烯酸酯接枝聚丙烯中空纤维膜的pH依赖性

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The pH dependence of poly (acrylic acid)-graft-polypropylene membranes were evaluated. The result shows that pH sensitivity of grafted membranes increases with the rise of grafting degree (dg) as dg<17%. For the microfiltration of Bovine serum albumin (BSA) solution, all membranes show the most serious fouling behavior at pH 4.7 (the isoelectric point IEP of BSA) and the smallest flux decline at pH 3. Compared with the ungrafted PP membrane, grafted membranes show more serious fouling behavior at pH 3, whereas 18% grafted membrane has a certain antifouling behavior at pH 4.7 and 8. It has been shown that the electrical interactions and the conformation of BSA and grafted chains should be considered to analyze the fouling behavior.
机译:评价了聚(丙烯酸)-接枝-聚丙烯膜的pH依赖性。结果表明,当dg <17%时,接枝膜的pH敏感性随接枝度(dg)的增加而增加。对于牛血清白蛋白(BSA)溶液的微滤,所有膜在pH 4.7(BSA的等电点IEP)时表现出最严重的结垢行为,在pH 3时通量下降最小。 pH 3时更严重的结垢行为,而18%的接枝膜在pH 4.7和8时具有一定的防垢行为。已经表明,应考虑电相互作用以及BSA和接枝链的构象来分析结垢行为。

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