USING SURF ACE-ACTIVE HETEROFUNCTIONAL OLIGOMERIC PEROXIDES FOR IMPROVEMENT OF MICRO- AND MACRO CHARACTERISTICS OF INORGANIC PLATE FLAT SURFACE

摘要

Surface activity and reactivity of functional surface-active oligoperoxides (FSAP) and derived metal complexes (OMC) with side di tertiary peroxide fragments, respectively and reactive hydroxyl, carboxyl, siliceous or epoxide groups provide the possibility of their utilization as surface-active multi-center radical initiators, modifiers of phase boundaries of liquid, solid and mixed phases and, thereby, as prospective surface modifiers and free radical sources for initiation of graft-polymerization onto previously modified surface. The experimental results of the investigations of polymer formation by monomers of different nature in the result of heterogeneous graft- polymerization initiated by OMC attached to plate surface, which provides the formation of irreversibly tethered to the surface polymer layers of tailored nature, are presented in the paper.