首页> 外文会议>Symposium on scientific basis for nuclear waste management >Gadolinium solubility limits in sodium-alumino-borosilicate glasses
【24h】

Gadolinium solubility limits in sodium-alumino-borosilicate glasses

机译:钠铝硼硅酸盐玻璃中solubility的溶解度极限

获取原文

摘要

Gadolinium and lanthanum solubility limits in a sodium-alumino-borosilicate glass system were studied. As melting temperature increased from 1400 deg C to 1450 deg C, 1500 deg C and 1550 deg C, the solubility of gadolinium in the baseline glass 15B)2O_3-5Al_2O_3-20Na_2O-60SiG_2 (in molar composition) increased from 10.1 to 11.3, 12.2 and 13.1 (in mole percent of Gd_2O_3). The enthalpy change of Gd_2O_3 dissolution in this baseline glass is about 43.6 kJ/mol. Boron effect on lanthanum solubility was studied using the following baseline glasses: xB_2O_3-20Na_2O-5Al_2O_3-60SiO_2, where x equals to 5, 10, 15, and 20, respectively. It was found that lanthanum solubility limit increased from 8.4 to 10.3, 12.5 and 14.9 (in mole percent of La_2O_3) as B_2O_3 increased from 5.1 to 9.5, 13.1 and 16.2 mol
机译:研究了钠铝硼硅玻璃体系中d和镧的溶解度极限。随着熔融温度从1400摄氏度增加到1450摄氏度,1500摄氏度和1550摄氏度,g在基线玻璃15B)2O_3-5Al_2O_3-20Na_2O-60SiG_2(摩尔组成)中的溶解度从10.1增至11.3、12.2。和13.1(以Gd_2O_3的摩尔百分比计)。在该基线玻璃中,Gd_2O_3溶解的焓变约为43.6 kJ / mol。使用以下基准玻璃研究硼对镧溶解度的影响:xB_2O_3-20Na_2O-5Al_2O_3-60SiO_2,其中x分别等于5、10、15和20。发现随着B_2O_3从5.1摩尔增加到9.5、13.1和16.2摩尔,镧的溶解度极限从8.4增加到10.3、12.5和14.9(以La_2O_3的摩尔百分比计)。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号