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Gadolinium solubility limits in sodium-alumino-borosilicate glasses

机译:钆溶解度在铝硼硅酸钠玻璃中的溶解度限制

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Gadolinium and lanthanum solubility limits in a sodium-alumino-borosilicate glass system were studied. As melting temperature increased from 1400 deg C to 1450 deg C, 1500 deg C and 1550 deg C, the solubility of gadolinium in the baseline glass 15B)2O_3-5Al_2O_3-20Na_2O-60SiG_2 (in molar composition) increased from 10.1 to 11.3, 12.2 and 13.1 (in mole percent of Gd_2O_3). The enthalpy change of Gd_2O_3 dissolution in this baseline glass is about 43.6 kJ/mol. Boron effect on lanthanum solubility was studied using the following baseline glasses: xB_2O_3-20Na_2O-5Al_2O_3-60SiO_2, where x equals to 5, 10, 15, and 20, respectively. It was found that lanthanum solubility limit increased from 8.4 to 10.3, 12.5 and 14.9 (in mole percent of La_2O_3) as B_2O_3 increased from 5.1 to 9.5, 13.1 and 16.2 mol
机译:研究了亚铝 - 硼硅酸钠玻璃系统中的钆和镧溶解度限制。随着熔融温度从1400℃至1450℃,1500℃和1550℃增加,钆在基线玻璃15b中的溶解度20_3-5al_2O_3-20na_2O-60sig_2(摩尔组合物)从10.1增加到11.3,12.2和13.1(以gd_2o_3的摩尔%)。在该基线玻璃中Gd_2O_3溶解的焓变为约43.6kJ / mol。使用以下基线玻璃研究了硼对镧溶解度的影响:Xb_2O_3-20na_2O-5Al_2O_3-60sio_2,其中x等于5,10,15和20。发现镧溶解度极限从8.4增加到10.4-10.3,12.5和14.9(以La_2O_3的摩尔百分比)增加,因为B_2O_3从5.1增加到9.5,13.1和16.2摩尔

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